Enhancement of CO2 uptake and selectivity in a metal-organic framework by incorporation of thiophene functionality

Enhancement of CO2 uptake and selectivity in a metal-organic framework by incorporation of thiophene functionality

The complex [Zn2(tdc)2dabco] (H2tdc = thiophene-2,5-dicarboxylic acid; dabco = 1,4-diazabicyclooctane) shows a remarkable increase in CO2 uptake and CO2/N2 selectivity compared to the non-thiophene analogue [Zn2(bdc)2dabco] (H2bdc = benzene-1,4-dicarboxylic acid; terephthalic acid). CO2 adsorption...

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Bibliographic Details
Main Authors: Bolotov, Vsevolod A., Kovalenko, Konstantin A., Samsonenko, Denis G., Han, Xue, Zhang, Xinran, Smith, Gemma L., McCormick, Laura, Teat, Simon J., Yang, Sihai, Lennox, Matthew J., Henley, Alice, Besley, Elena, Fedin, Vladimir P., Dybtsev, Danil N., Schröder, Martin
Format: Article
Published: American Chemical Society 2018
Subjects:
Carbon dioxide
metal-organic framework
thiophene
carboxylate
zinc
binding site
breakthrough
Online Access:https://eprints.nottingham.ac.uk/52663/

Internet

https://eprints.nottingham.ac.uk/52663/

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