Enantioselective nickel-catalyzed arylative intramolecular 1,4allylations
The enantioselective nickel-catalyzed desymmetrization of allenyl cyclohexa-2,5-dienones by reaction with arylboronic acids is described. Nickel-catalyzed arylation of the allene gives allylnickel species, which undergo cyclization by 1,4allylation to produce hexahydroindol-5-ones and hexahydrofuran...
| Main Authors: | , , , |
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| Format: | Article |
| Published: |
Royal Society of Chemistry
2018
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| Online Access: | https://eprints.nottingham.ac.uk/51692/ |