Synthesis and properties of open fullerenes encapsulating
ammonia and methane

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Synthesis and properties of open fullerenes encapsulating ammonia and methane

We describe the synthesis and characterisation of open fullerene (1) and its reduced form (2) in which CH₄ and NH₃ are encapsulated, respectively. The ¹H NMR resonance of endohedral NH₃ is broadened by scalar coupling to the quadrupolar ¹⁴N nucleus, which relaxes rapidly. This broadening is absent f...

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Bibliographic Details
Main Authors:	Bloodworth, Sally, Gräsvik, John, Alom, Shamim, Kouril,, Karel, Elliott, Stuart J., Wells, Neil J., Horsewill, Anthony J., Mamone, Salvatore, Jimenez-Ruiz, Monica, Rols, Stéphane, Nagel, Urmas, Room, Toomas, Levitt, Malcolm H., Whitby, Richard J.
Format:	Article
Published:	Wiley 2018
Subjects:	endofullerenes; inelastic neutron scattering spectroscopy; infra-red spectroscopy; NMR spectroscopy; SpinDynamica
Online Access:	https://eprints.nottingham.ac.uk/50033/

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