Synthesis and properties of open fullerenes encapsulating ammonia and methane
We describe the synthesis and characterisation of open fullerene (1) and its reduced form (2) in which CH₄ and NH₃ are encapsulated, respectively. The ¹H NMR resonance of endohedral NH₃ is broadened by scalar coupling to the quadrupolar ¹⁴N nucleus, which relaxes rapidly. This broadening is absent f...
| Main Authors: | , , , , , , , , , , , , , |
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| Format: | Article |
| Published: |
Wiley
2018
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| Subjects: | |
| Online Access: | https://eprints.nottingham.ac.uk/50033/ |