Heterobimetallic [NiFe] complexes containing mixed CO/CN− ligands: analogs of the active site of the [NiFe] hydrogenases

The development of synthetic analogs of the active sites of [NiFe] hydrogenases remains challenging and, in spite of the number of complexes featuring a [NiFe] center, those featuring CO and CN− ligands at the Fe center are under-represented. We report herein the synthesis of three bimetallic [NiFe]...

Full description

Bibliographic Details
Main Authors: Perotto, Carlo U., Sodipo, Charlene L., Jones, Graham J., Tidey, Jeremiah P., Blake, Alexander J., Lewis, William, Davies, E. Stephen, McMaster, Jonathan, Schröder, Martin
Format: Article
Published: American Chemical Society 2018
Online Access:https://eprints.nottingham.ac.uk/50008/