Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

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Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation....

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Bibliographic Details
Main Authors:	Nolla-Saltiel, Roberto, Geer, Ana M, Lewis, William, Blake, Alexander J., Kays, Deborah L.
Format:	Article
Published:	Royal Society of Chemistry 2018
Online Access:	https://eprints.nottingham.ac.uk/49825/

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