Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes
Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation....
| Main Authors: | , , , , |
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| Format: | Article |
| Published: |
Royal Society of Chemistry
2018
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| Online Access: | https://eprints.nottingham.ac.uk/49825/ |