Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes
Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation....
| Main Authors: | , , , , |
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| Format: | Article |
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Royal Society of Chemistry
2018
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| Online Access: | https://eprints.nottingham.ac.uk/49825/ |
| _version_ | 1848798086613172224 |
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| author | Nolla-Saltiel, Roberto Geer, Ana M Lewis, William Blake, Alexander J. Kays, Deborah L. |
| author_facet | Nolla-Saltiel, Roberto Geer, Ana M Lewis, William Blake, Alexander J. Kays, Deborah L. |
| author_sort | Nolla-Saltiel, Roberto |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation. |
| first_indexed | 2025-11-14T20:14:11Z |
| format | Article |
| id | nottingham-49825 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T20:14:11Z |
| publishDate | 2018 |
| publisher | Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-498252020-05-04T19:33:32Z https://eprints.nottingham.ac.uk/49825/ Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes Nolla-Saltiel, Roberto Geer, Ana M Lewis, William Blake, Alexander J. Kays, Deborah L. Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation. Royal Society of Chemistry 2018-02-21 Article PeerReviewed Nolla-Saltiel, Roberto, Geer, Ana M, Lewis, William, Blake, Alexander J. and Kays, Deborah L. (2018) Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes. Chemical Communications, 54 (15). pp. 1825-1828. ISSN 1364-548X http://pubs.rsc.org/en/content/articlelanding/2018/cc/c7cc08385h#!divAbstract doi:10.1039/c7cc08385h doi:10.1039/c7cc08385h |
| spellingShingle | Nolla-Saltiel, Roberto Geer, Ana M Lewis, William Blake, Alexander J. Kays, Deborah L. Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes |
| title | Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes |
| title_full | Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes |
| title_fullStr | Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes |
| title_full_unstemmed | Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes |
| title_short | Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes |
| title_sort | dehydrogenation of dimethylamine-borane mediated by group 1 pincer complexes |
| url | https://eprints.nottingham.ac.uk/49825/ https://eprints.nottingham.ac.uk/49825/ https://eprints.nottingham.ac.uk/49825/ |