Unusual and tunable negative linear compressibility in the metal–organic framework MFM-133(M)(M = Zr, Hf)

High pressure single-crystal X-ray structural analyses of isostructural MFM-133(M) (M = Zr, Hf) of flu topology and incorporating the tetracarboxylate ligand TCHB4– [H4TCHB = 3,3',5,5'-tetrakis(4-carboxyphenyl)-2,2',4,4',6,6'-hexamethyl-1,1'-biphenyl] and {M6(μ-OH)8(OH)...

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Bibliographic Details
Main Authors: Yan, Yong, O'Connor, Alice E., Kanthasamy, Gopikkaa, Atkinson, George, Allan, David R., Blake, Alexander J., Schröder, Martin
Format: Article
Published: American Chemical Society 2018
Online Access:https://eprints.nottingham.ac.uk/49819/