Probing the carbon-hydrogen activation of alkanes following photolysis of Tp’Rh(CNR)(carbodiimide): a computational and time-resolved infrared spectroscopic study

Probing the carbon-hydrogen activation of alkanes following photolysis of Tp’Rh(CNR)(carbodiimide): a computational and time-resolved infrared spectroscopic study

Carbon–hydrogen bond activation reactions of alkanes by Tp’Rh(CNR) (Tp’ = Tp = trispyrazolylborate or Tp* = tris(3,5-dimethylpyrazolyl)borate) were followed by timeresolved infrared spectroscopy (TRIR) in the υ(CNR) and υ(BH) spectral regions on Tp*Rh(CNCH2CMe3), and their reaction mechanisms were m...

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Bibliographic Details
Main Authors: Guan, Jia, Wriglesworth, Alisdair, Brothers, Edward N., Snežana, D. Zarić, Jones, William D., Hall, Michael B., George, Michael W.
Format: Article
Published: American Chemical Society 2017
Online Access:https://eprints.nottingham.ac.uk/49578/

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