Probing the carbon-hydrogen activation of alkanes following photolysis of Tp’Rh(CNR)(carbodiimide): a computational and time-resolved infrared spectroscopic study
Carbon–hydrogen bond activation reactions of alkanes by Tp’Rh(CNR) (Tp’ = Tp = trispyrazolylborate or Tp* = tris(3,5-dimethylpyrazolyl)borate) were followed by timeresolved infrared spectroscopy (TRIR) in the υ(CNR) and υ(BH) spectral regions on Tp*Rh(CNCH2CMe3), and their reaction mechanisms were m...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Published: |
American Chemical Society
2017
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| Online Access: | https://eprints.nottingham.ac.uk/49578/ |