Biochemical analysis of Hel308 and HelQ helicases

DNA replication is an essential process conducted by the replisome. This large protein complex is continually challenged by DNA insults which hamper progression resulting in replication fork stalling or collapse. Paused replication forks contribute to a state of genome instability which is a major h...

Full description

Bibliographic Details
Main Author: Buckley, Ryan J.
Format: Thesis (University of Nottingham only)
Language:English
Published: 2017
Online Access:https://eprints.nottingham.ac.uk/47926/
_version_ 1848797651087130624
author Buckley, Ryan J.
author_facet Buckley, Ryan J.
author_sort Buckley, Ryan J.
building Nottingham Research Data Repository
collection Online Access
description DNA replication is an essential process conducted by the replisome. This large protein complex is continually challenged by DNA insults which hamper progression resulting in replication fork stalling or collapse. Paused replication forks contribute to a state of genome instability which is a major hazard for cells. Hel308 and HelQ are superfamily 2 helicases thought to promote genome stability in archaea and metazoans by acting at stalled replication forks. They participate in the early stages of recombination repair, responding to damage caused by DNA interstrand crosslinks. Both proteins are single stranded DNA stimulated ATPases which preferentially unwind forked DNA conferring a 3’ to 5’ polarity. DNA translocation is thought to occur through step wise movement of the helicase core, coupled to the actions of an accessory ratchet domain. These proteins possess an unconventional winged helix domain of unknown function. Protein/DNA interactions required for unwinding were investigated using chemically modified DNA substrates. Archaeal Hel308 showed sensitivity to an abasic site within the single stranded region and a methylphosphonate within the duplex region, suggesting essential base-stacking and electrostatic interactions. Human HelQ data contrasted this, eluding to a reliance on interactions within the duplex region. DNA binding affinities were also investigated using fluorescence anisotropy. Data suggested a role for Hel308 WHD in binding flayed duplex DNA and confirmed HelQ is able to bind a variety of DNA substrates. A third helicase; LHR, was successfully purified with the aim to collect single-molecule data as part of a collaboration.
first_indexed 2025-11-14T20:07:16Z
format Thesis (University of Nottingham only)
id nottingham-47926
institution University of Nottingham Malaysia Campus
institution_category Local University
language English
last_indexed 2025-11-14T20:07:16Z
publishDate 2017
recordtype eprints
repository_type Digital Repository
spelling nottingham-479262025-02-28T13:55:01Z https://eprints.nottingham.ac.uk/47926/ Biochemical analysis of Hel308 and HelQ helicases Buckley, Ryan J. DNA replication is an essential process conducted by the replisome. This large protein complex is continually challenged by DNA insults which hamper progression resulting in replication fork stalling or collapse. Paused replication forks contribute to a state of genome instability which is a major hazard for cells. Hel308 and HelQ are superfamily 2 helicases thought to promote genome stability in archaea and metazoans by acting at stalled replication forks. They participate in the early stages of recombination repair, responding to damage caused by DNA interstrand crosslinks. Both proteins are single stranded DNA stimulated ATPases which preferentially unwind forked DNA conferring a 3’ to 5’ polarity. DNA translocation is thought to occur through step wise movement of the helicase core, coupled to the actions of an accessory ratchet domain. These proteins possess an unconventional winged helix domain of unknown function. Protein/DNA interactions required for unwinding were investigated using chemically modified DNA substrates. Archaeal Hel308 showed sensitivity to an abasic site within the single stranded region and a methylphosphonate within the duplex region, suggesting essential base-stacking and electrostatic interactions. Human HelQ data contrasted this, eluding to a reliance on interactions within the duplex region. DNA binding affinities were also investigated using fluorescence anisotropy. Data suggested a role for Hel308 WHD in binding flayed duplex DNA and confirmed HelQ is able to bind a variety of DNA substrates. A third helicase; LHR, was successfully purified with the aim to collect single-molecule data as part of a collaboration. 2017-12-12 Thesis (University of Nottingham only) NonPeerReviewed application/pdf en arr https://eprints.nottingham.ac.uk/47926/1/Ryan%20Buckley_%20MRes%20Thesis_4280151.pdf Buckley, Ryan J. (2017) Biochemical analysis of Hel308 and HelQ helicases. MRes thesis, University of Nottingham.
spellingShingle Buckley, Ryan J.
Biochemical analysis of Hel308 and HelQ helicases
title Biochemical analysis of Hel308 and HelQ helicases
title_full Biochemical analysis of Hel308 and HelQ helicases
title_fullStr Biochemical analysis of Hel308 and HelQ helicases
title_full_unstemmed Biochemical analysis of Hel308 and HelQ helicases
title_short Biochemical analysis of Hel308 and HelQ helicases
title_sort biochemical analysis of hel308 and helq helicases
url https://eprints.nottingham.ac.uk/47926/