1,4-addition of TMSCCl3to nitroalkenes: efficient reaction conditions and mechanistic understanding
Improved synthetic conditions allow preparation of TMSCCl3 in good yield (70 %) and excellent purity. Compounds of the type NBu4X [X=Ph3SiF2 (TBAT), F (tetrabutylammonium fluoride, TBAF), OAc, Cl and Br] act as catalytic promoters for 1,4-additions to a range of cyclic and acyclic nitroalkenes, in T...
| Main Authors: | , , , |
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| Format: | Article |
| Published: |
Wiley-VCH Verlag
2014
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| Subjects: | |
| Online Access: | https://eprints.nottingham.ac.uk/46650/ |