Total synthesis of (−)-aritasone via the ultra-high pressure hetero-Diels–Alder dimerisation of (−)-pinocarvone
This paper describes a total synthesis of the terpene-derived natural product aritasone via the hetero-Diels-Alder [4+2] cyclodimerisation of pinocarvove, which represents the proposed biosyntheic route. The hetero-Diels-Alder dimerisation of pinocarvone did not proceed under standard conditions, a...
| Main Authors: | , , , , , |
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| Format: | Article |
| Published: |
Royal Society of Chemistry
2017
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| Online Access: | https://eprints.nottingham.ac.uk/46603/ |