Probing the use of long lived intra-ligand π-π * excited states for photocatalytic systems: a study of the photophysics and photochemistry of [ReCl(CO)3(dppz-(CH3)2)]

Probing the use of long lived intra-ligand π-π * excited states for photocatalytic systems: a study of the photophysics and photochemistry of [ReCl(CO)3(dppz-(CH3)2)]

We report the excited state photophysics and photochemistry of [ReCl(CO)3(dppz-(CH3)2)] (dppz-(CH3)2 = 11,12-dimethyl-dipyrido[3,2-a:2’,3’-c]phenazine) in CH3CN using timeresolved infrared (TRIR) and Fourier transform infrared (FTIR) spectroscopy. Excitation of the 1MLCT (metal-to-ligand charge tran...

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Bibliographic Details
Main Authors: Summers, Peter A., Calladine, James A., Ibrahim, Nasiru, Kusumo, Kennedy P., Clark, Charlotte A., Sun, Xue-Z., Hamilton, Michelle L., Towrie, Michael, McMaster, Jonathan, Schröder, Martin, George, Michael W.
Format: Article
Published: Elsevier 2017
Subjects:
Rhenium ; Time-resolved IR ; Photophysics ; Intra-ligand excited state ; Reductive quenching
Online Access:https://eprints.nottingham.ac.uk/45837/

Internet

https://eprints.nottingham.ac.uk/45837/

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