Nanoscale ultrasound-switchable FRET based liposomes for near-infrared fluorescence imaging in optically turbid media

A new approach to fluorescence imaging in optically turbid media centered on the use of nanoscale ultrasound-switchable FRET based liposome contrast agents is reported. Liposomes containing lipophilic carbocyanine dyes as FRET pairs with emission wavelengths located in the near-infrared window were...

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Main Authors: Zhang, Qimei, Morgan, Stephen P., Mather, Melissa L.
Format: Article
Published: Wiley-VCH Verlag 2017
Subjects:
Online Access:https://eprints.nottingham.ac.uk/45836/
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author Zhang, Qimei
Morgan, Stephen P.
Mather, Melissa L.
author_facet Zhang, Qimei
Morgan, Stephen P.
Mather, Melissa L.
author_sort Zhang, Qimei
building Nottingham Research Data Repository
collection Online Access
description A new approach to fluorescence imaging in optically turbid media centered on the use of nanoscale ultrasound-switchable FRET based liposome contrast agents is reported. Liposomes containing lipophilic carbocyanine dyes as FRET pairs with emission wavelengths located in the near-infrared window were prepared. The efficacy of FRET and self-quenching for liposomes with a range of fluorophore concentrations was first calculated from measurement of the liposome emission spectra. Exposure of the liposomes to ultrasound resulted in changes in the detected fluorescent signal, the nature of which depending on the fluorophores used, detection wavelength and the fluorophore concentration. Line scanning of a tube containing the contrast agents with 1 mm inner diameter buried at a depth of 1 cm in a heavily scattering tissue phantom demonstrated an improvement in image spatial resolution by a factor of 6.3 as compared with images obtained in the absence of ultrasound. Improvements were also seen in image contrast with the highest obtained being 9% for a liposome system containing FRET pairs. Overall the results obtained provide evidence of the potential the nanoscale ultrasound-switchable FRET based liposomes studied here have for in vivo fluorescence imaging.
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spelling nottingham-458362020-05-04T19:05:12Z https://eprints.nottingham.ac.uk/45836/ Nanoscale ultrasound-switchable FRET based liposomes for near-infrared fluorescence imaging in optically turbid media Zhang, Qimei Morgan, Stephen P. Mather, Melissa L. A new approach to fluorescence imaging in optically turbid media centered on the use of nanoscale ultrasound-switchable FRET based liposome contrast agents is reported. Liposomes containing lipophilic carbocyanine dyes as FRET pairs with emission wavelengths located in the near-infrared window were prepared. The efficacy of FRET and self-quenching for liposomes with a range of fluorophore concentrations was first calculated from measurement of the liposome emission spectra. Exposure of the liposomes to ultrasound resulted in changes in the detected fluorescent signal, the nature of which depending on the fluorophores used, detection wavelength and the fluorophore concentration. Line scanning of a tube containing the contrast agents with 1 mm inner diameter buried at a depth of 1 cm in a heavily scattering tissue phantom demonstrated an improvement in image spatial resolution by a factor of 6.3 as compared with images obtained in the absence of ultrasound. Improvements were also seen in image contrast with the highest obtained being 9% for a liposome system containing FRET pairs. Overall the results obtained provide evidence of the potential the nanoscale ultrasound-switchable FRET based liposomes studied here have for in vivo fluorescence imaging. Wiley-VCH Verlag 2017-09-06 Article PeerReviewed Zhang, Qimei, Morgan, Stephen P. and Mather, Melissa L. (2017) Nanoscale ultrasound-switchable FRET based liposomes for near-infrared fluorescence imaging in optically turbid media. Small, 13 (33). 1602895/1-1602895/12. ISSN 1613-6829 FRET; liposome; nanoscale; near-infrared; ultrasound switchable fluorescence tomography http://onlinelibrary.wiley.com/doi/10.1002/smll.201602895/abstract;jsessionid=5D8A8F2BC4480655EEE4D71CF5BC557F.f03t01 doi:10.1002/smll.201602895 doi:10.1002/smll.201602895
spellingShingle FRET; liposome; nanoscale; near-infrared; ultrasound switchable fluorescence tomography
Zhang, Qimei
Morgan, Stephen P.
Mather, Melissa L.
Nanoscale ultrasound-switchable FRET based liposomes for near-infrared fluorescence imaging in optically turbid media
title Nanoscale ultrasound-switchable FRET based liposomes for near-infrared fluorescence imaging in optically turbid media
title_full Nanoscale ultrasound-switchable FRET based liposomes for near-infrared fluorescence imaging in optically turbid media
title_fullStr Nanoscale ultrasound-switchable FRET based liposomes for near-infrared fluorescence imaging in optically turbid media
title_full_unstemmed Nanoscale ultrasound-switchable FRET based liposomes for near-infrared fluorescence imaging in optically turbid media
title_short Nanoscale ultrasound-switchable FRET based liposomes for near-infrared fluorescence imaging in optically turbid media
title_sort nanoscale ultrasound-switchable fret based liposomes for near-infrared fluorescence imaging in optically turbid media
topic FRET; liposome; nanoscale; near-infrared; ultrasound switchable fluorescence tomography
url https://eprints.nottingham.ac.uk/45836/
https://eprints.nottingham.ac.uk/45836/
https://eprints.nottingham.ac.uk/45836/