Versatile C(sp2)−C(sp3) ligand couplings of sulfoxides for the enantioselective synthesis of diarylalkanes

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Versatile C(sp2)−C(sp3) ligand couplings of sulfoxides for the enantioselective synthesis of diarylalkanes

The reaction of chiral (hetero)aryl benzyl sulfoxides with Grignard reagents affords enantiomerically pure diarylalkanes in up to 98% yield and greater than 99.5% enantiomeric excess. This ligand coupling reaction is tolerant to multiple substitution patterns and provides access to diverse areas of...

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Bibliographic Details
Main Authors:	Dean, William Michael, Mindaugas, Šiaučiulis, Storr, Thomas E., Lewis, William, Stockman, Robert A.
Format:	Article
Published:	Wiley-VCH Verlag 2016
Subjects:	sp2-sp3 coupling Sulfoxide Ligand coupling Diarylmethane Sulfurane
Online Access:	https://eprints.nottingham.ac.uk/42752/

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