Sigmatropic rearrangement of vinyl aziridines: expedient synthesis of cyclic sulfoximines from chiral sulfinimines
A novel rearrangement of 2-vinyl aziridine 2-carboxylates to unusual chiral cyclic sulfoximines is described herein. The method allows the synthesis of substituted cyclic sulfoximines in high yields with complete stereocontrol, displaying a wide substrate scope under mild conditions. Further develo...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Published: |
Wiley-VCH Verlag
2016
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| Online Access: | https://eprints.nottingham.ac.uk/42559/ |