Iron(II) catalyzed hydrophosphination of isocyanates

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Iron(II) catalyzed hydrophosphination of isocyanates

The first transition metal catalyzed hydrophosphination of isocyanates is presented. The use of low-coordinate iron(II) precatalysts leads to an unprecedented catalytic double insertion of isocyanates into the P-H bond of diphenylphosphine to yield phosphinodicarboxamides [Ph2PC(=O)N(R)C(=O)N(H)R],...

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Bibliographic Details
Main Authors:	Sharpe, Helen R., Geer, Ana M., Lewis, William, Blake, Alexander J., Kays, Deborah L.
Format:	Article
Published:	Wiley-VCH Verlag 2017
Subjects:	Hydrophosphination Iron Isocyanates m-terphenyl ligands Homogeneous catalysis
Online Access:	https://eprints.nottingham.ac.uk/41735/

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