Iron(II) catalyzed hydrophosphination of isocyanates
The first transition metal catalyzed hydrophosphination of isocyanates is presented. The use of low-coordinate iron(II) precatalysts leads to an unprecedented catalytic double insertion of isocyanates into the P-H bond of diphenylphosphine to yield phosphinodicarboxamides [Ph2PC(=O)N(R)C(=O)N(H)R],...
| Main Authors: | , , , , |
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| Format: | Article |
| Published: |
Wiley-VCH Verlag
2017
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| Subjects: | |
| Online Access: | https://eprints.nottingham.ac.uk/41735/ |