Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings

High chromium content in Ni50Cr thermally sprayed coatings can generate a dense and protective scale at the surface of coating. Thus, the Ni50Cr coating is widely used in high temperature oxidation and corrosion applications. A commercially available gas atomized Ni50Cr powder was sprayed onto a pow...

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Main Authors: Song, B., Bai, M., Voisey, K.T., Hussain, Tanvir
Format: Article
Published: Springer 2017
Subjects:
Online Access:https://eprints.nottingham.ac.uk/40026/
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author Song, B.
Bai, M.
Voisey, K.T.
Hussain, Tanvir
author_facet Song, B.
Bai, M.
Voisey, K.T.
Hussain, Tanvir
author_sort Song, B.
building Nottingham Research Data Repository
collection Online Access
description High chromium content in Ni50Cr thermally sprayed coatings can generate a dense and protective scale at the surface of coating. Thus, the Ni50Cr coating is widely used in high temperature oxidation and corrosion applications. A commercially available gas atomized Ni50Cr powder was sprayed onto a power plant steel (ASME P92) using a liquid fuelled high velocity oxy-fuel (HVOF) thermal spray with three processing parameters in this study. Microstructure of as-sprayed coatings was examined using oxygen content analysis, mercury intrusion porosimetry (MIP), scanning electron microscope (SEM), Energy-dispersive X-ray spectroscopy (EDX) and X-ray Diffraction (XRD). Short-term air oxidation tests (4 h) of freestanding coatings (without boiler steel substrate) in a thermogravimetric analyser (TGA) at 700 ℃ were performed to obtain the kinetics of oxidation of the as-sprayed coating. Long-term air oxidation tests (100 h) of the coated substrates were performed at same temperature to obtain the oxidation products for further characterization in detail using SEM / EDX and XRD. In all samples, oxides of various morphologies developed on top of the Ni50Cr coatings. Cr₂O₃ was the main oxidation product on the surface of all three coatings. The coating with medium porosity and medium oxygen content has the best high temperature oxidation performance in this study.
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spelling nottingham-400262020-05-04T18:29:09Z https://eprints.nottingham.ac.uk/40026/ Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings Song, B. Bai, M. Voisey, K.T. Hussain, Tanvir High chromium content in Ni50Cr thermally sprayed coatings can generate a dense and protective scale at the surface of coating. Thus, the Ni50Cr coating is widely used in high temperature oxidation and corrosion applications. A commercially available gas atomized Ni50Cr powder was sprayed onto a power plant steel (ASME P92) using a liquid fuelled high velocity oxy-fuel (HVOF) thermal spray with three processing parameters in this study. Microstructure of as-sprayed coatings was examined using oxygen content analysis, mercury intrusion porosimetry (MIP), scanning electron microscope (SEM), Energy-dispersive X-ray spectroscopy (EDX) and X-ray Diffraction (XRD). Short-term air oxidation tests (4 h) of freestanding coatings (without boiler steel substrate) in a thermogravimetric analyser (TGA) at 700 ℃ were performed to obtain the kinetics of oxidation of the as-sprayed coating. Long-term air oxidation tests (100 h) of the coated substrates were performed at same temperature to obtain the oxidation products for further characterization in detail using SEM / EDX and XRD. In all samples, oxides of various morphologies developed on top of the Ni50Cr coatings. Cr₂O₃ was the main oxidation product on the surface of all three coatings. The coating with medium porosity and medium oxygen content has the best high temperature oxidation performance in this study. Springer 2017-01-31 Article PeerReviewed Song, B., Bai, M., Voisey, K.T. and Hussain, Tanvir (2017) Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings. Journal of Thermal Spray Technology . ISSN 1544-1016 HVOF Ni50Cr Processing parameter Microstructure Oxidation Cr₂O₃ NiCr₂O₄ http://link.springer.com/article/10.1007/s11666-017-0531-z doi:10.1007/s11666-017-0531-z doi:10.1007/s11666-017-0531-z
spellingShingle HVOF
Ni50Cr
Processing parameter
Microstructure
Oxidation
Cr₂O₃
NiCr₂O₄
Song, B.
Bai, M.
Voisey, K.T.
Hussain, Tanvir
Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings
title Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings
title_full Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings
title_fullStr Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings
title_full_unstemmed Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings
title_short Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings
title_sort role of oxides and porosity on high temperature oxidation of liquid fuelled hvof thermal sprayed ni50cr coatings
topic HVOF
Ni50Cr
Processing parameter
Microstructure
Oxidation
Cr₂O₃
NiCr₂O₄
url https://eprints.nottingham.ac.uk/40026/
https://eprints.nottingham.ac.uk/40026/
https://eprints.nottingham.ac.uk/40026/