Pickering particles prepared from food waste

In this paper, we demonstrate the functionality and functionalisation of waste particles as an emulsifier for oil-in-water (o/w) and water-in-oil (w/o) emulsions. Ground coffee waste was chosen as a candidate waste material due to its naturally high content of lignin, a chemical component imparting...

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Main Authors: Gould, Joanne, Garcia-Garcia, Guillermo, Wolf, Bettina
Format: Article
Published: MDPI 2016
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Online Access:https://eprints.nottingham.ac.uk/37032/
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author Gould, Joanne
Garcia-Garcia, Guillermo
Wolf, Bettina
author_facet Gould, Joanne
Garcia-Garcia, Guillermo
Wolf, Bettina
author_sort Gould, Joanne
building Nottingham Research Data Repository
collection Online Access
description In this paper, we demonstrate the functionality and functionalisation of waste particles as an emulsifier for oil-in-water (o/w) and water-in-oil (w/o) emulsions. Ground coffee waste was chosen as a candidate waste material due to its naturally high content of lignin, a chemical component imparting emulsifying ability. The waste coffee particles readily stabilised o/w emulsions and following hydrothermal treatment adapted from the bioenergy field they also stabilised w/o emulsions. The hydrothermal treatment relocated the lignin component of the cell walls within the coffee particles onto the particle surface thereby increasing the surface hydrophobicity of the particles as demonstrated by an emulsion assay. Emulsion droplet sizes were comparable to those found in processed foods in the case of hydrophilic waste coffee particles stabilizing o/w emulsions. These emulsions were stable against coalescence for at least 12 weeks, flocculated but stable against coalescence in shear and stable to pasteurisation conditions (10 min at 80 °C). Emulsion droplet size was also insensitive to pH of the aqueous phase during preparation (pH 3–pH 9). Stable against coalescence, the water droplets in w/o emulsions prepared with hydrothermally treated waste coffee particles were considerably larger and microscopic examination showed evidence of arrested coalescence indicative of particle jamming at the surface of the emulsion droplets. Refinement of the hydrothermal treatment and broadening out to other lignin-rich plant or plant based food waste material are promising routes to bring closer the development of commercially relevant lignin based food Pickering particles applicable to emulsion based processed foods ranging from fat continuous spreads and fillings to salad dressings.
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spelling nottingham-370322020-05-04T18:10:14Z https://eprints.nottingham.ac.uk/37032/ Pickering particles prepared from food waste Gould, Joanne Garcia-Garcia, Guillermo Wolf, Bettina In this paper, we demonstrate the functionality and functionalisation of waste particles as an emulsifier for oil-in-water (o/w) and water-in-oil (w/o) emulsions. Ground coffee waste was chosen as a candidate waste material due to its naturally high content of lignin, a chemical component imparting emulsifying ability. The waste coffee particles readily stabilised o/w emulsions and following hydrothermal treatment adapted from the bioenergy field they also stabilised w/o emulsions. The hydrothermal treatment relocated the lignin component of the cell walls within the coffee particles onto the particle surface thereby increasing the surface hydrophobicity of the particles as demonstrated by an emulsion assay. Emulsion droplet sizes were comparable to those found in processed foods in the case of hydrophilic waste coffee particles stabilizing o/w emulsions. These emulsions were stable against coalescence for at least 12 weeks, flocculated but stable against coalescence in shear and stable to pasteurisation conditions (10 min at 80 °C). Emulsion droplet size was also insensitive to pH of the aqueous phase during preparation (pH 3–pH 9). Stable against coalescence, the water droplets in w/o emulsions prepared with hydrothermally treated waste coffee particles were considerably larger and microscopic examination showed evidence of arrested coalescence indicative of particle jamming at the surface of the emulsion droplets. Refinement of the hydrothermal treatment and broadening out to other lignin-rich plant or plant based food waste material are promising routes to bring closer the development of commercially relevant lignin based food Pickering particles applicable to emulsion based processed foods ranging from fat continuous spreads and fillings to salad dressings. MDPI 2016-09-21 Article PeerReviewed Gould, Joanne, Garcia-Garcia, Guillermo and Wolf, Bettina (2016) Pickering particles prepared from food waste. Materials, 9 (791). pp. 1-14. ISSN 1996-1944 pickering emulsions; particles; lignin; food emulsions http://www.mdpi.com/1996-1944/9/9/791 doi:10.3390/ma9090791 doi:10.3390/ma9090791
spellingShingle pickering emulsions; particles; lignin; food emulsions
Gould, Joanne
Garcia-Garcia, Guillermo
Wolf, Bettina
Pickering particles prepared from food waste
title Pickering particles prepared from food waste
title_full Pickering particles prepared from food waste
title_fullStr Pickering particles prepared from food waste
title_full_unstemmed Pickering particles prepared from food waste
title_short Pickering particles prepared from food waste
title_sort pickering particles prepared from food waste
topic pickering emulsions; particles; lignin; food emulsions
url https://eprints.nottingham.ac.uk/37032/
https://eprints.nottingham.ac.uk/37032/
https://eprints.nottingham.ac.uk/37032/