Rhodium-catalyzed oxidative C–H allylation of benzamides with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration
The Rh(III)-catalyzed oxidative C–H allylation of N-acetylbenzamides with 1,3-dienes is described. The presence of allylic hydrogens cis- to the less substituted alkene of the 1,3-diene is important for the success of these reactions. With the assistance of reactions using deuterated 1,3-dienes, a p...
| Main Authors: | , , |
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| Format: | Article |
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American Chemical Society
2016
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| Online Access: | https://eprints.nottingham.ac.uk/36246/ |
| _version_ | 1848795250762448896 |
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| author | Korkis, Stamatis E. Burns, David J. Lam, Hon Wai |
| author_facet | Korkis, Stamatis E. Burns, David J. Lam, Hon Wai |
| author_sort | Korkis, Stamatis E. |
| building | Nottingham Research Data Repository |
| collection | Online Access |
| description | The Rh(III)-catalyzed oxidative C–H allylation of N-acetylbenzamides with 1,3-dienes is described. The presence of allylic hydrogens cis- to the less substituted alkene of the 1,3-diene is important for the success of these reactions. With the assistance of reactions using deuterated 1,3-dienes, a proposed mechanism is provided. The key step is postulated to be the first reported examples of allyl-to-allyl 1,4-Rh(III) migration. |
| first_indexed | 2025-11-14T19:29:06Z |
| format | Article |
| id | nottingham-36246 |
| institution | University of Nottingham Malaysia Campus |
| institution_category | Local University |
| last_indexed | 2025-11-14T19:29:06Z |
| publishDate | 2016 |
| publisher | American Chemical Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | nottingham-362462020-05-04T18:06:15Z https://eprints.nottingham.ac.uk/36246/ Rhodium-catalyzed oxidative C–H allylation of benzamides with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration Korkis, Stamatis E. Burns, David J. Lam, Hon Wai The Rh(III)-catalyzed oxidative C–H allylation of N-acetylbenzamides with 1,3-dienes is described. The presence of allylic hydrogens cis- to the less substituted alkene of the 1,3-diene is important for the success of these reactions. With the assistance of reactions using deuterated 1,3-dienes, a proposed mechanism is provided. The key step is postulated to be the first reported examples of allyl-to-allyl 1,4-Rh(III) migration. American Chemical Society 2016-08-22 Article PeerReviewed Korkis, Stamatis E., Burns, David J. and Lam, Hon Wai (2016) Rhodium-catalyzed oxidative C–H allylation of benzamides with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration. Journal of the American Chemical Society . ISSN 1520-5126 http://pubs.acs.org/doi/abs/10.1021/jacs.6b06884 doi:10.1021/jacs.6b06884 doi:10.1021/jacs.6b06884 |
| spellingShingle | Korkis, Stamatis E. Burns, David J. Lam, Hon Wai Rhodium-catalyzed oxidative C–H allylation of benzamides with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration |
| title | Rhodium-catalyzed oxidative C–H allylation of benzamides
with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration |
| title_full | Rhodium-catalyzed oxidative C–H allylation of benzamides
with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration |
| title_fullStr | Rhodium-catalyzed oxidative C–H allylation of benzamides
with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration |
| title_full_unstemmed | Rhodium-catalyzed oxidative C–H allylation of benzamides
with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration |
| title_short | Rhodium-catalyzed oxidative C–H allylation of benzamides
with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration |
| title_sort | rhodium-catalyzed oxidative c–h allylation of benzamides
with 1,3-dienes by allyl-to-allyl 1,4-rh(iii) migration |
| url | https://eprints.nottingham.ac.uk/36246/ https://eprints.nottingham.ac.uk/36246/ https://eprints.nottingham.ac.uk/36246/ |