Rhodium-catalyzed oxidative C–H allylation of benzamides with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration

The Rh(III)-catalyzed oxidative C–H allylation of N-acetylbenzamides with 1,3-dienes is described. The presence of allylic hydrogens cis- to the less substituted alkene of the 1,3-diene is important for the success of these reactions. With the assistance of reactions using deuterated 1,3-dienes, a p...

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Bibliographic Details
Main Authors: Korkis, Stamatis E., Burns, David J., Lam, Hon Wai
Format: Article
Published: American Chemical Society 2016
Online Access:https://eprints.nottingham.ac.uk/36246/