In-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced Raman spectroscopy by dielectrophoresis

We report the use of dielectrophoresis to fabricate in-situ probes for tip-enhanced Raman spectroscopy (TERS) based on Au nanoparticles. A typical conductive atomic force microscope (AFM) was used to functionalize iridium-coated conductive silicon probes with Au nanoparticles of 10-nm diameter. Suit...

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Main Authors: Sweetenham, Claire Sue, Woolley, Richard, Notingher, Ioan
Format: Article
Published: Society of Photo-optical Instrumentation Engineers 2016
Subjects:
Online Access:https://eprints.nottingham.ac.uk/36186/
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author Sweetenham, Claire Sue
Woolley, Richard
Notingher, Ioan
author_facet Sweetenham, Claire Sue
Woolley, Richard
Notingher, Ioan
author_sort Sweetenham, Claire Sue
building Nottingham Research Data Repository
collection Online Access
description We report the use of dielectrophoresis to fabricate in-situ probes for tip-enhanced Raman spectroscopy (TERS) based on Au nanoparticles. A typical conductive atomic force microscope (AFM) was used to functionalize iridium-coated conductive silicon probes with Au nanoparticles of 10-nm diameter. Suitable TERS probes can be rapidly produced (30 to 120 s) by applying a voltage of 10 Vpp at a frequency of 1 MHz. The technique has the advantage that the Au-based probes are ready for immediate use for TERS measurements, minimizing the risks of tip contamination and damage during handling. Scanning electron microscopy and energy dispersive x-ray spectroscopy were used to confirm the quality of the probes, and used samples of p-ATP monolayers on silver substrates were used to demonstrate experimentally TERS measurements.
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spelling nottingham-361862020-05-04T18:06:37Z https://eprints.nottingham.ac.uk/36186/ In-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced Raman spectroscopy by dielectrophoresis Sweetenham, Claire Sue Woolley, Richard Notingher, Ioan We report the use of dielectrophoresis to fabricate in-situ probes for tip-enhanced Raman spectroscopy (TERS) based on Au nanoparticles. A typical conductive atomic force microscope (AFM) was used to functionalize iridium-coated conductive silicon probes with Au nanoparticles of 10-nm diameter. Suitable TERS probes can be rapidly produced (30 to 120 s) by applying a voltage of 10 Vpp at a frequency of 1 MHz. The technique has the advantage that the Au-based probes are ready for immediate use for TERS measurements, minimizing the risks of tip contamination and damage during handling. Scanning electron microscopy and energy dispersive x-ray spectroscopy were used to confirm the quality of the probes, and used samples of p-ATP monolayers on silver substrates were used to demonstrate experimentally TERS measurements. Society of Photo-optical Instrumentation Engineers 2016-08-18 Article PeerReviewed Sweetenham, Claire Sue, Woolley, Richard and Notingher, Ioan (2016) In-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced Raman spectroscopy by dielectrophoresis. Journal of Nanophotonics, 10 (3). 030502. ISSN 1934-2608 tip-enhanced Raman spectroscopy; dielectrophoresis; gold nanoparticles http://nanophotonics.spiedigitallibrary.org/article.aspx?articleid=2546056 10.1117/1.JNP.10.030502 10.1117/1.JNP.10.030502 10.1117/1.JNP.10.030502
spellingShingle tip-enhanced Raman spectroscopy; dielectrophoresis; gold nanoparticles
Sweetenham, Claire Sue
Woolley, Richard
Notingher, Ioan
In-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced Raman spectroscopy by dielectrophoresis
title In-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced Raman spectroscopy by dielectrophoresis
title_full In-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced Raman spectroscopy by dielectrophoresis
title_fullStr In-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced Raman spectroscopy by dielectrophoresis
title_full_unstemmed In-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced Raman spectroscopy by dielectrophoresis
title_short In-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced Raman spectroscopy by dielectrophoresis
title_sort in-situ fabrication of gold nanoparticle functionalized probes for tip-enhanced raman spectroscopy by dielectrophoresis
topic tip-enhanced Raman spectroscopy; dielectrophoresis; gold nanoparticles
url https://eprints.nottingham.ac.uk/36186/
https://eprints.nottingham.ac.uk/36186/
https://eprints.nottingham.ac.uk/36186/