Hybrid tantalum oxide nanoparticles from the hydrolysis of imidazolium tantalate ionic liquids: efficient catalysts for hydrogen generation from ethanol/water solutions

The reaction of equimolar amounts of 1-n-butyl-3-methylimidazolium chloride (BMI·Cl) or 1-n-decyl-3-methylimidazolium chloride (DMI·Cl) with TaCl5 affords imidazolium tantalate ionic liquids (ILs) BMI·TaCl61 and DMI·TaCl62. The hydrolysis of ILs 1 and 2 yields hybrid-like tantalum oxide nanoparticle...

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Bibliographic Details
Main Authors: Souza, Virginia S., Scholten, Jackson D., Weibel, Daniel E., Eberhardt, Dario, Baptista, Daniel L., Teixeira, Sergio R., Dupont, Jairton
Format: Article
Published: Royal Society of Chemistry 2016
Online Access:https://eprints.nottingham.ac.uk/35855/