Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study

High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, whi...

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Main Authors: O'Connor, Alice E., Mirzadeh, Nedaossadat, Bhargava, Suresh, Easun, Timothy L., Schröder, Martin, Blake, Alexander J.
Format: Article
Published: Royal Society of Chemistry 2016
Subjects:
Online Access:https://eprints.nottingham.ac.uk/35540/
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author O'Connor, Alice E.
Mirzadeh, Nedaossadat
Bhargava, Suresh
Easun, Timothy L.
Schröder, Martin
Blake, Alexander J.
author_facet O'Connor, Alice E.
Mirzadeh, Nedaossadat
Bhargava, Suresh
Easun, Timothy L.
Schröder, Martin
Blake, Alexander J.
author_sort O'Connor, Alice E.
building Nottingham Research Data Repository
collection Online Access
description High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.
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institution University of Nottingham Malaysia Campus
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last_indexed 2025-11-14T19:26:45Z
publishDate 2016
publisher Royal Society of Chemistry
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spelling nottingham-355402020-05-04T17:42:07Z https://eprints.nottingham.ac.uk/35540/ Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study O'Connor, Alice E. Mirzadeh, Nedaossadat Bhargava, Suresh Easun, Timothy L. Schröder, Martin Blake, Alexander J. High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure. Royal Society of Chemistry 2016-03-11 Article PeerReviewed O'Connor, Alice E., Mirzadeh, Nedaossadat, Bhargava, Suresh, Easun, Timothy L., Schröder, Martin and Blake, Alexander J. (2016) Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. Chemical Communications, 52 . pp. 6769-6772. ISSN 1364-548X High pressure gold complexes structure determination spectroscopy intermolecular interactions http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00923A#!divAbstract doi:10.1039/C6CC00923A doi:10.1039/C6CC00923A
spellingShingle High pressure
gold complexes
structure determination
spectroscopy
intermolecular interactions
O'Connor, Alice E.
Mirzadeh, Nedaossadat
Bhargava, Suresh
Easun, Timothy L.
Schröder, Martin
Blake, Alexander J.
Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study
title Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study
title_full Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study
title_fullStr Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study
title_full_unstemmed Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study
title_short Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study
title_sort aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study
topic High pressure
gold complexes
structure determination
spectroscopy
intermolecular interactions
url https://eprints.nottingham.ac.uk/35540/
https://eprints.nottingham.ac.uk/35540/
https://eprints.nottingham.ac.uk/35540/