Surface chemistry of Ti6Al4V components fabricated using selective laser melting for biomedical applications

Selective laser melting (SLM) has previously been shown to be a viable method for fabricating biomedical implants; however, the surface chemistry of SLM fabricated parts is poorly understood. In this study, X-ray photoelectron spectroscopy (XPS) was used to determine the surface chemistries of (a) S...

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Main Authors: Vaithilingam, Jayasheelan, Prina, Elisabetta, Goodridge, Ruth D., Hague, Richard J.M., Edmondson, Steve, Rose, Felicity R.A.J., Christie, Steven D.R.
Format: Article
Published: Elsevier 2016
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Online Access:https://eprints.nottingham.ac.uk/33425/
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author Vaithilingam, Jayasheelan
Prina, Elisabetta
Goodridge, Ruth D.
Hague, Richard J.M.
Edmondson, Steve
Rose, Felicity R.A.J.
Christie, Steven D.R.
author_facet Vaithilingam, Jayasheelan
Prina, Elisabetta
Goodridge, Ruth D.
Hague, Richard J.M.
Edmondson, Steve
Rose, Felicity R.A.J.
Christie, Steven D.R.
author_sort Vaithilingam, Jayasheelan
building Nottingham Research Data Repository
collection Online Access
description Selective laser melting (SLM) has previously been shown to be a viable method for fabricating biomedical implants; however, the surface chemistry of SLM fabricated parts is poorly understood. In this study, X-ray photoelectron spectroscopy (XPS) was used to determine the surface chemistries of (a) SLM as-fabricated (SLM-AF) Ti6Al4V and (b) SLM fabricated and mechanically polished (SLM-MP) Ti6Al4V samples and compared with (c) traditionally manufactured (forged) and mechanically polished Ti6Al4V samples. The SLM– AF surface was observed to be porous with an average surface roughness (Ra) of 17.6 ± 3.7 μm. The surface chemistry of the SLM-AF was significantly different to the FGD-MP surface with respect to elemental distribution and their existence on the outermost surface Sintered particles on the SLM-AF surface were observed to affect depth profiling of the sample due to a shadowing effect during argon ion sputtering. Surface heterogeneity was observed for all three surfaces; however, vanadium was witnessed only on the mechanically polished (SLM-MP and FGD-MP) surfaces. The direct and indirect 3T3 cell cytotoxicity studies revealed that the cells were viable on the SLM fabricated Ti6Al4V parts. The varied surface chemistry of the SLM-AF and SLM-MP did not influence the cell behaviour.
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spelling nottingham-334252020-05-04T18:08:38Z https://eprints.nottingham.ac.uk/33425/ Surface chemistry of Ti6Al4V components fabricated using selective laser melting for biomedical applications Vaithilingam, Jayasheelan Prina, Elisabetta Goodridge, Ruth D. Hague, Richard J.M. Edmondson, Steve Rose, Felicity R.A.J. Christie, Steven D.R. Selective laser melting (SLM) has previously been shown to be a viable method for fabricating biomedical implants; however, the surface chemistry of SLM fabricated parts is poorly understood. In this study, X-ray photoelectron spectroscopy (XPS) was used to determine the surface chemistries of (a) SLM as-fabricated (SLM-AF) Ti6Al4V and (b) SLM fabricated and mechanically polished (SLM-MP) Ti6Al4V samples and compared with (c) traditionally manufactured (forged) and mechanically polished Ti6Al4V samples. The SLM– AF surface was observed to be porous with an average surface roughness (Ra) of 17.6 ± 3.7 μm. The surface chemistry of the SLM-AF was significantly different to the FGD-MP surface with respect to elemental distribution and their existence on the outermost surface Sintered particles on the SLM-AF surface were observed to affect depth profiling of the sample due to a shadowing effect during argon ion sputtering. Surface heterogeneity was observed for all three surfaces; however, vanadium was witnessed only on the mechanically polished (SLM-MP and FGD-MP) surfaces. The direct and indirect 3T3 cell cytotoxicity studies revealed that the cells were viable on the SLM fabricated Ti6Al4V parts. The varied surface chemistry of the SLM-AF and SLM-MP did not influence the cell behaviour. Elsevier 2016-10-01 Article PeerReviewed Vaithilingam, Jayasheelan, Prina, Elisabetta, Goodridge, Ruth D., Hague, Richard J.M., Edmondson, Steve, Rose, Felicity R.A.J. and Christie, Steven D.R. (2016) Surface chemistry of Ti6Al4V components fabricated using selective laser melting for biomedical applications. Materials Science and Engineering: C, 67 . pp. 294-303. ISSN 0928-4931 Additive manufacturing; 3D printing; Selective laser melting (SLM); Surface chemistry; Ti6Al4V; Cytotoxicity http://www.sciencedirect.com/science/article/pii/S0928493116304738 10.1016/j.msec.2016.05.054 10.1016/j.msec.2016.05.054 10.1016/j.msec.2016.05.054
spellingShingle Additive manufacturing; 3D printing; Selective laser melting (SLM); Surface chemistry; Ti6Al4V; Cytotoxicity
Vaithilingam, Jayasheelan
Prina, Elisabetta
Goodridge, Ruth D.
Hague, Richard J.M.
Edmondson, Steve
Rose, Felicity R.A.J.
Christie, Steven D.R.
Surface chemistry of Ti6Al4V components fabricated using selective laser melting for biomedical applications
title Surface chemistry of Ti6Al4V components fabricated using selective laser melting for biomedical applications
title_full Surface chemistry of Ti6Al4V components fabricated using selective laser melting for biomedical applications
title_fullStr Surface chemistry of Ti6Al4V components fabricated using selective laser melting for biomedical applications
title_full_unstemmed Surface chemistry of Ti6Al4V components fabricated using selective laser melting for biomedical applications
title_short Surface chemistry of Ti6Al4V components fabricated using selective laser melting for biomedical applications
title_sort surface chemistry of ti6al4v components fabricated using selective laser melting for biomedical applications
topic Additive manufacturing; 3D printing; Selective laser melting (SLM); Surface chemistry; Ti6Al4V; Cytotoxicity
url https://eprints.nottingham.ac.uk/33425/
https://eprints.nottingham.ac.uk/33425/
https://eprints.nottingham.ac.uk/33425/