Photochemical dihydrogen production using an analogue of the active site of [NiFe] hydrogenase

Photochemical dihydrogen production using an analogue of the active site of [NiFe] hydrogenase

The photoproduction of dihydrogen (H2) by a low molecular weight analogue of the active site of [NiFe] hydrogenase has been investigated by the reduction of the [NiFe2] cluster, 1, by a photosensitier PS (PS = [ReCl(CO)3(bpy)] or [Ru(bpy)3][PF6]2). Reductive quenching of the 3MLCT excited state of t...

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Bibliographic Details
Main Authors: Summers, Peter A., Dawson, Joe, Ghiotto, Fabio, Hanson-Heine, Magnus W.D., Vuong, Khuong Q., Davies, E. Stephen, Sun, Xue-Z., Besley, Nicholas A., McMaster, Jonathan, George, Michael W., Schröder, Martin
Format: Article
Published: American Chemical Society 2014
Subjects:
Hydrogenase
rhenium
nickel
iron
thiolate
time-resolved IR
proton reduction
Online Access:https://eprints.nottingham.ac.uk/29703/

Internet

https://eprints.nottingham.ac.uk/29703/

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