A novel bismuth-based metal-organic framework for high volumetric methane and carbon dioxide adsorption
Solvothermal reaction of H4L (L = biphenyl-3,3’,5,5’-tetracarboxylate) and Bi(NO3)3·(H2O)5 in a mixture of DMF/MeCN/H2O in the presence of piperazine and nitric acid at 100 oC for 10 h affords the solvated metal-organic polymer [Bi2(L)1.5(H2O)2]·(DMF)3.5·(H2O)3 (NOTT-220-solv). A single crystal X-ra...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Published: |
Wiley-VCH Verlag
2014
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| Subjects: | |
| Online Access: | https://eprints.nottingham.ac.uk/29699/ |