High pressure studies of palladium and platinum thioether macrocyclic dihalide complexes

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High pressure studies of palladium and platinum thioether macrocyclic dihalide complexes

The mononuclear macrocyclic Pd(II) complex cis-[PdCl2([9 aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane) converts at 44 kbar into an intensely coloured chain polymer exhibiting distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether ligand. The...

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Bibliographic Details
Main Author:	Schröder, Martin
Format:	Article
Published:	International Union of Crystallography 2014
Subjects:	High pressure; coordination complexes; palladium; platinum; macrocycle; intermolecular contacts; conformation; polymerisation
Online Access:	https://eprints.nottingham.ac.uk/29689/

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