High pressure studies of palladium and platinum thioether macrocyclic dihalide complexes
The mononuclear macrocyclic Pd(II) complex cis-[PdCl2([9 aneS3)] ([9]aneS3 = 1,4,7-trithiacyclononane) converts at 44 kbar into an intensely coloured chain polymer exhibiting distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether ligand. The...
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| Format: | Article |
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International Union of Crystallography
2014
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| Online Access: | https://eprints.nottingham.ac.uk/29689/ |