HM+ and HM+‑He (M = Group 2 metal): chemical or physical interactions?

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HM+ and HM+‑He (M = Group 2 metal): chemical or physical interactions?

We investigate the HM+–He complexes (M = Group 2 metal) using quantum chemistry. Equilibrium geometries are linear for M = Be and Mg, and bent for M = Ca–Ra; the explanation for this lies in the differing nature of the highest occupied molecular orbitals in the two sets of complexes. The difference...

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Bibliographic Details
Main Authors:	Harris, Joe P., Dodson, Hannah, Breckenridge, W.H., Wright, Timothy G.
Format:	Article
Published:	American Institute of Physics 2014
Online Access:	https://eprints.nottingham.ac.uk/28797/

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