Characterization of soft-combustion-derived NASICON-type Li2Co2(MoO4)3 for lithium batteries
This work describes the synthesis of a new polyanion material, Li(2)CO(2)(MoO(4))(3), belonging to the NASICON family. A low-temperature soft-combustion method using glycine as a soft-combustion fuel was adopted to obtain single-phase powders of the new material at a temperature as low as 300degrees...
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| Format: | Article |
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2004
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| Online Access: | http://shdl.mmu.edu.my/2436/ |
| _version_ | 1848790055860043776 |
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| author | PRABAHARAN, S |
| author_facet | PRABAHARAN, S |
| author_sort | PRABAHARAN, S |
| building | MMU Institutional Repository |
| collection | Online Access |
| description | This work describes the synthesis of a new polyanion material, Li(2)CO(2)(MoO(4))(3), belonging to the NASICON family. A low-temperature soft-combustion method using glycine as a soft-combustion fuel was adopted to obtain single-phase powders of the new material at a temperature as low as 300degreesC. Li(2)Co(2)(MoO(4))(3,) was found to crystallize in an orthorhombic structure (space group Pmmm) with lattice parameters a = 17.584(7) A, b = 10.464(4) A and c = 5.102(9) A. The electronic state of each element present in the new material was confirmed by X-ray photoelectron spectroscopic analysis. The powders were analyzed using inductively coupled plasma emission spectroscopy. The microstructural analysis revealed that the particles (5-10 mum) have a rather columnar shape. The electrochemistry redox behavior of. the new material was studied, for the first time, and the material as positive electrode was found to exhibit topotactic Li(+) extraction/insertion in lithium-containing test cells. (C) 2004 Elsevier B.V. All rights reserved. |
| first_indexed | 2025-11-14T18:06:32Z |
| format | Article |
| id | mmu-2436 |
| institution | Multimedia University |
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| last_indexed | 2025-11-14T18:06:32Z |
| publishDate | 2004 |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | mmu-24362011-08-22T02:02:49Z http://shdl.mmu.edu.my/2436/ Characterization of soft-combustion-derived NASICON-type Li2Co2(MoO4)3 for lithium batteries PRABAHARAN, S Q Science (General) This work describes the synthesis of a new polyanion material, Li(2)CO(2)(MoO(4))(3), belonging to the NASICON family. A low-temperature soft-combustion method using glycine as a soft-combustion fuel was adopted to obtain single-phase powders of the new material at a temperature as low as 300degreesC. Li(2)Co(2)(MoO(4))(3,) was found to crystallize in an orthorhombic structure (space group Pmmm) with lattice parameters a = 17.584(7) A, b = 10.464(4) A and c = 5.102(9) A. The electronic state of each element present in the new material was confirmed by X-ray photoelectron spectroscopic analysis. The powders were analyzed using inductively coupled plasma emission spectroscopy. The microstructural analysis revealed that the particles (5-10 mum) have a rather columnar shape. The electrochemistry redox behavior of. the new material was studied, for the first time, and the material as positive electrode was found to exhibit topotactic Li(+) extraction/insertion in lithium-containing test cells. (C) 2004 Elsevier B.V. All rights reserved. 2004-10 Article NonPeerReviewed PRABAHARAN, S (2004) Characterization of soft-combustion-derived NASICON-type Li2Co2(MoO4)3 for lithium batteries. Materials Chemistry and Physics, 87 (2-3). pp. 318-326. ISSN 02540584 http://dx.doi.org/10.1016/j.matchemphys.2004.05.041 doi:10.1016/j.matchemphys.2004.05.041 doi:10.1016/j.matchemphys.2004.05.041 |
| spellingShingle | Q Science (General) PRABAHARAN, S Characterization of soft-combustion-derived NASICON-type Li2Co2(MoO4)3 for lithium batteries |
| title | Characterization of soft-combustion-derived NASICON-type Li2Co2(MoO4)3 for lithium batteries |
| title_full | Characterization of soft-combustion-derived NASICON-type Li2Co2(MoO4)3 for lithium batteries |
| title_fullStr | Characterization of soft-combustion-derived NASICON-type Li2Co2(MoO4)3 for lithium batteries |
| title_full_unstemmed | Characterization of soft-combustion-derived NASICON-type Li2Co2(MoO4)3 for lithium batteries |
| title_short | Characterization of soft-combustion-derived NASICON-type Li2Co2(MoO4)3 for lithium batteries |
| title_sort | characterization of soft-combustion-derived nasicon-type li2co2(moo4)3 for lithium batteries |
| topic | Q Science (General) |
| url | http://shdl.mmu.edu.my/2436/ http://shdl.mmu.edu.my/2436/ http://shdl.mmu.edu.my/2436/ |