Electrochemical oxidation of D-fructose solution using the Box–Behnken design methodology
The electrochemical oxidation of D-fructose solution was studied using a Box–Behnken design. Seventeen batch runs of electrochemical oxidation were conducted based on three sets of operating conditions generated using Design-Expert software. The effects of D-fructose concentration, applied voltage a...
| Main Authors: | , |
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| Format: | Journal Article |
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Taylor & Francis Ltd.
2014
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| Online Access: | http://hdl.handle.net/20.500.11937/9420 |
| _version_ | 1848745945422888960 |
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| author | Tay, Chen Lim Fam, S.L. |
| author_facet | Tay, Chen Lim Fam, S.L. |
| author_sort | Tay, Chen Lim |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The electrochemical oxidation of D-fructose solution was studied using a Box–Behnken design. Seventeen batch runs of electrochemical oxidation were conducted based on three sets of operating conditions generated using Design-Expert software. The effects of D-fructose concentration, applied voltage and NaOH concentration on oxidation percentage and oxidation rate were studied. As revealed by ANOVA, the D-fructose and NaOH concentrations significantly affected the oxidation percentage, and the applied voltage and NaOH concentration significantly affected the oxidation rate. Functional models for the oxidation percentage and oxidation rate were generated and reported. The electrochemical oxidation of D-fructose was optimised by maximising the D-fructose concentration and minimising the applied voltage and NaOH concentration. The models were validated by comparing the adjusted optimised solution with the experimental data. A 62.78% electrochemical oxidation percentage and an oxidation rate of 12.20 mM/L h were achieved using 82% D-fructose with 0.14 M NaOH and a 10 V applied voltage. |
| first_indexed | 2025-11-14T06:25:25Z |
| format | Journal Article |
| id | curtin-20.500.11937-9420 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T06:25:25Z |
| publishDate | 2014 |
| publisher | Taylor & Francis Ltd. |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-94202017-09-13T14:52:44Z Electrochemical oxidation of D-fructose solution using the Box–Behnken design methodology Tay, Chen Lim Fam, S.L. Box–Behnken Electrochemical oxidation Wastewater treatment D-fructose Optimisation Modelling The electrochemical oxidation of D-fructose solution was studied using a Box–Behnken design. Seventeen batch runs of electrochemical oxidation were conducted based on three sets of operating conditions generated using Design-Expert software. The effects of D-fructose concentration, applied voltage and NaOH concentration on oxidation percentage and oxidation rate were studied. As revealed by ANOVA, the D-fructose and NaOH concentrations significantly affected the oxidation percentage, and the applied voltage and NaOH concentration significantly affected the oxidation rate. Functional models for the oxidation percentage and oxidation rate were generated and reported. The electrochemical oxidation of D-fructose was optimised by maximising the D-fructose concentration and minimising the applied voltage and NaOH concentration. The models were validated by comparing the adjusted optimised solution with the experimental data. A 62.78% electrochemical oxidation percentage and an oxidation rate of 12.20 mM/L h were achieved using 82% D-fructose with 0.14 M NaOH and a 10 V applied voltage. 2014 Journal Article http://hdl.handle.net/20.500.11937/9420 10.1080/19443994.2014.880380 Taylor & Francis Ltd. restricted |
| spellingShingle | Box–Behnken Electrochemical oxidation Wastewater treatment D-fructose Optimisation Modelling Tay, Chen Lim Fam, S.L. Electrochemical oxidation of D-fructose solution using the Box–Behnken design methodology |
| title | Electrochemical oxidation of D-fructose solution using the Box–Behnken design methodology |
| title_full | Electrochemical oxidation of D-fructose solution using the Box–Behnken design methodology |
| title_fullStr | Electrochemical oxidation of D-fructose solution using the Box–Behnken design methodology |
| title_full_unstemmed | Electrochemical oxidation of D-fructose solution using the Box–Behnken design methodology |
| title_short | Electrochemical oxidation of D-fructose solution using the Box–Behnken design methodology |
| title_sort | electrochemical oxidation of d-fructose solution using the box–behnken design methodology |
| topic | Box–Behnken Electrochemical oxidation Wastewater treatment D-fructose Optimisation Modelling |
| url | http://hdl.handle.net/20.500.11937/9420 |