Synthesis, reactivity and preliminary biological activity of iron(0) complexes with cyclopentadienone and amino-appended N-heterocyclic carbene ligands

Synthesis, reactivity and preliminary biological activity of iron(0) complexes with cyclopentadienone and amino-appended N-heterocyclic carbene ligands

Neutral and cationic cyclopentadienone (CpO) N-heterocyclic carbene (NHC) bis-carbonyl iron(0) complexes bearing, appended to the NHC ligand, either a terminal amino group on the lateral chain, [Fe(η 4 -CpO)(CO) 2 (κC-NHC(CH 2 ) n NH 2 )] with n = 2 (2a) and 3 (2b), or a cationic NMe 3+ fragment, [F...

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Bibliographic Details
Main Authors: Cingolani, A., Zanotti, V., Zacchini, S., Massi, Max, Simpson, Peter, Maheshkumar Desai, N., Casari, I., Falasca, Marco, Rigamonti, L., Mazzoni, R.
Format: Journal Article
Language:English
Published: WILEY 2019
Subjects:
Science & Technology
Physical Sciences
Chemistry, Applied
Chemistry, Inorganic & Nuclear
Chemistry
cyclopentadienone
cytotoxicity
Iron(0) complexes
N-heterocyclic carbene
photoactivation
STRUCTURE VALIDATION
METAL-COMPLEXES
ACTIVATION
RUTHENIUM
Online Access:http://purl.org/au-research/grants/arc/FT130100033
http://hdl.handle.net/20.500.11937/92001

Internet

http://purl.org/au-research/grants/arc/FT130100033
http://hdl.handle.net/20.500.11937/92001

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