Electrostatic Regulation of TEMPO Oxidation by Distal Molecular Charges

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Electrostatic Regulation of TEMPO Oxidation by Distal Molecular Charges

We define, experimentally, the effect of intramolecular electric fields, generated from the positive charge of ferricenium cations, over the oxidation potential of 2,2,6,6-tetramethyl-1-piperdinyloxy (TEMPO). We synthesized a TEMPO derivative, where the nitroxide is linked to a ferrocene unit. We ha...

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Bibliographic Details
Main Authors:	Zhang, L., Ciampi, Simone, Gooding, J.J.
Format:	Journal Article
Language:	English
Published:	WILEY-V C H VERLAG GMBH 2020
Subjects:	Science & Technology Physical Sciences Electrochemistry nitroxide potential separation ferricenium charges electrostatic regulation electrical double layer ORIENTED ELECTRIC-FIELDS CATALYSIS SELECTIVITY MONOLAYERS
Online Access:	http://purl.org/au-research/grants/arc/CE140100036 http://hdl.handle.net/20.500.11937/91722

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