Electrostatic Regulation of TEMPO Oxidation by Distal Molecular Charges

Electrostatic Regulation of TEMPO Oxidation by Distal Molecular Charges

We define, experimentally, the effect of intramolecular electric fields, generated from the positive charge of ferricenium cations, over the oxidation potential of 2,2,6,6-tetramethyl-1-piperdinyloxy (TEMPO). We synthesized a TEMPO derivative, where the nitroxide is linked to a ferrocene unit. We ha...

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Bibliographic Details
Main Authors: Zhang, L., Ciampi, Simone, Gooding, J.J.
Format: Journal Article
Language:English
Published: WILEY-V C H VERLAG GMBH 2020
Subjects:
Science & Technology
Physical Sciences
Electrochemistry
nitroxide
potential separation
ferricenium charges
electrostatic regulation
electrical double layer
ORIENTED ELECTRIC-FIELDS
CATALYSIS
SELECTIVITY
MONOLAYERS
Online Access:http://purl.org/au-research/grants/arc/CE140100036
http://hdl.handle.net/20.500.11937/91722

Internet

http://purl.org/au-research/grants/arc/CE140100036
http://hdl.handle.net/20.500.11937/91722

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