Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies
The preparation of discrete tetranuclear lanthanide/alkali metal (Ae) assemblies bearing a tribenzoylmethane ligand (LH) is discussed. These assemblies have the general formula [Ln(Ae·HOEt)(L)4]2, where Ln3+ = Gd3+, Tb3+, Dy3+, Ho3+ and Ae+ = Na+, K+, Rb+. The coordination geometries of the lanthani...
| Main Authors: | , , , , , , |
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| Format: | Journal Article |
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Taylor & Francis
2016
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| Online Access: | http://hdl.handle.net/20.500.11937/8944 |
| _version_ | 1848745807278243840 |
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| author | Reid, Brodie Woodward, R. Fuller, Rebecca Sobolev, A. Skelton, B. Ogden, Mark Massi, Massimiliano |
| author_facet | Reid, Brodie Woodward, R. Fuller, Rebecca Sobolev, A. Skelton, B. Ogden, Mark Massi, Massimiliano |
| author_sort | Reid, Brodie |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | The preparation of discrete tetranuclear lanthanide/alkali metal (Ae) assemblies bearing a tribenzoylmethane ligand (LH) is discussed. These assemblies have the general formula [Ln(Ae·HOEt)(L)4]2, where Ln3+ = Gd3+, Tb3+, Dy3+, Ho3+ and Ae+ = Na+, K+, Rb+. The coordination geometries of the lanthanide species were analyzed and compared, revealing a trend between an eight-coordinate square antiprism and triangular dodecahedron dependent on the nature of lanthanide, alkali metal, and lattice solvent. The potassium-containing analogs were also analyzed for their magnetic susceptibility. |
| first_indexed | 2025-11-14T06:23:13Z |
| format | Journal Article |
| id | curtin-20.500.11937-8944 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T06:23:13Z |
| publishDate | 2016 |
| publisher | Taylor & Francis |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-89442018-09-18T01:16:41Z Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies Reid, Brodie Woodward, R. Fuller, Rebecca Sobolev, A. Skelton, B. Ogden, Mark Massi, Massimiliano The preparation of discrete tetranuclear lanthanide/alkali metal (Ae) assemblies bearing a tribenzoylmethane ligand (LH) is discussed. These assemblies have the general formula [Ln(Ae·HOEt)(L)4]2, where Ln3+ = Gd3+, Tb3+, Dy3+, Ho3+ and Ae+ = Na+, K+, Rb+. The coordination geometries of the lanthanide species were analyzed and compared, revealing a trend between an eight-coordinate square antiprism and triangular dodecahedron dependent on the nature of lanthanide, alkali metal, and lattice solvent. The potassium-containing analogs were also analyzed for their magnetic susceptibility. 2016 Journal Article http://hdl.handle.net/20.500.11937/8944 10.1080/00958972.2016.1180375 Taylor & Francis fulltext |
| spellingShingle | Reid, Brodie Woodward, R. Fuller, Rebecca Sobolev, A. Skelton, B. Ogden, Mark Massi, Massimiliano Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies |
| title | Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies |
| title_full | Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies |
| title_fullStr | Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies |
| title_full_unstemmed | Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies |
| title_short | Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies |
| title_sort | investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies |
| url | http://hdl.handle.net/20.500.11937/8944 |