Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies

The preparation of discrete tetranuclear lanthanide/alkali metal (Ae) assemblies bearing a tribenzoylmethane ligand (LH) is discussed. These assemblies have the general formula [Ln(Ae·HOEt)(L)4]2, where Ln3+ = Gd3+, Tb3+, Dy3+, Ho3+ and Ae+ = Na+, K+, Rb+. The coordination geometries of the lanthani...

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Bibliographic Details
Main Authors: Reid, Brodie, Woodward, R., Fuller, Rebecca, Sobolev, A., Skelton, B., Ogden, Mark, Massi, Massimiliano
Format: Journal Article
Published: Taylor & Francis 2016
Online Access:http://hdl.handle.net/20.500.11937/8944