Impact of the carbon pore size and topology on the equilibrium quantum sieving of hydrogen isotopes at zero coverage and finite pressures
Carbonaceous slit-shaped and square-shaped pores efficiently differentiate adsorbed hydrogenisotopes at 77 and 33 K. Extensive path integral Monte Carlo simulations revealed that thesquare-shaped carbon pores enhanced the selectivity of deuterium over hydrogen in comparisonto equivalent slit-shaped...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Published: |
IOP Publishing Ltd
2009
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| Online Access: | http://stacks.iop.org/JPhysCM/21/144210 http://hdl.handle.net/20.500.11937/8941 |