Effect of Chemical Structure on the Electrochemical Cleavage of Alkoxyamines

A test set of 14 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO)-based alkoxyamines was studied via a combination of cyclic voltammetry and accurate quantum chemistry to assess the effect of substituents on electrochemical cleavage. The experimental oxidation potentials of alkoxyamines falling into the...

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Bibliographic Details
Main Authors: Hammill, C.L., Noble, B.B., Norcott, P.L., Ciampi, Simone, Coote, M.L.
Format: Journal Article
Language:English
Published: AMER CHEMICAL SOC 2019
Subjects:
Online Access:http://purl.org/au-research/grants/arc/FL170100041
http://hdl.handle.net/20.500.11937/80753