Mechanism of Oxidative Alkoxyamine Cleavage: The Surprising Role of the Solvent and Supporting Electrolyte

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Mechanism of Oxidative Alkoxyamine Cleavage: The Surprising Role of the Solvent and Supporting Electrolyte

In this work, we show that the nature of the supporting electrolyte and solvent can dramatically alter the outcome of the electrochemically mediated cleavage of alkoxyamines. A combination of cyclic voltammetry experiments and quantum chemistry is used to study the oxidation behavior of TEMPO-i-Pr u...

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Bibliographic Details
Main Authors:	Noble, B.B., Norcott, P.L., Hammill, C.L., Ciampi, Simone, Coote, M.L.
Format:	Journal Article
Language:	English
Published:	AMER CHEMICAL SOC 2019
Subjects:	Science & Technology Physical Sciences Technology Chemistry, Physical Nanoscience & Nanotechnology Materials Science, Multidisciplinary Chemistry Science & Technology - Other Topics Materials Science NITROXIDE-MEDIATED POLYMERIZATION CATIONIC-POLYMERIZATION ACETIC-ANHYDRIDE MOLECULAR-WEIGHT SIDE-REACTIONS ACTIVATION
Online Access:	http://purl.org/au-research/grants/arc/CE140100012 http://hdl.handle.net/20.500.11937/80752

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