Mechanism of Oxidative Alkoxyamine Cleavage: The Surprising Role of the Solvent and Supporting Electrolyte

Mechanism of Oxidative Alkoxyamine Cleavage: The Surprising Role of the Solvent and Supporting Electrolyte

In this work, we show that the nature of the supporting electrolyte and solvent can dramatically alter the outcome of the electrochemically mediated cleavage of alkoxyamines. A combination of cyclic voltammetry experiments and quantum chemistry is used to study the oxidation behavior of TEMPO-i-Pr u...

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Bibliographic Details
Main Authors: Noble, B.B., Norcott, P.L., Hammill, C.L., Ciampi, Simone, Coote, M.L.
Format: Journal Article
Language:English
Published: AMER CHEMICAL SOC 2019
Subjects:
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Nanoscience & Nanotechnology
Materials Science, Multidisciplinary
Chemistry
Science & Technology - Other Topics
Materials Science
NITROXIDE-MEDIATED POLYMERIZATION
CATIONIC-POLYMERIZATION
ACETIC-ANHYDRIDE
MOLECULAR-WEIGHT
SIDE-REACTIONS
ACTIVATION
Online Access:http://purl.org/au-research/grants/arc/CE140100012
http://hdl.handle.net/20.500.11937/80752

Internet

http://purl.org/au-research/grants/arc/CE140100012
http://hdl.handle.net/20.500.11937/80752

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