Nitrogen-doped graphic carbon protected Cu/Co/CoO nanoparticles for ultrasensitive and stable non-enzymatic determination of glucose and fructose in wine

© 2018 The Electrochemical Society. Food safety has always been a very serious and global concern. Content determination of each component is one of the most routine analyses in food testing. Here, nitrogen-doped graphic carbon (NGC)-coated Cu/Co/CoO nanoparticles (Cu/Co/CoO/NGC) show excellent...

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Main Authors: He, J., Zhong, Yijun, Xu, Q., Sun, H., Zhou, W., Shao, Zongping
Format: Journal Article
Language:English
Published: ELECTROCHEMICAL SOC INC 2018
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/79274
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author He, J.
Zhong, Yijun
Xu, Q.
Sun, H.
Zhou, W.
Shao, Zongping
author_facet He, J.
Zhong, Yijun
Xu, Q.
Sun, H.
Zhou, W.
Shao, Zongping
author_sort He, J.
building Curtin Institutional Repository
collection Online Access
description © 2018 The Electrochemical Society. Food safety has always been a very serious and global concern. Content determination of each component is one of the most routine analyses in food testing. Here, nitrogen-doped graphic carbon (NGC)-coated Cu/Co/CoO nanoparticles (Cu/Co/CoO/NGC) show excellent performance for glucose and fructose detection in wine. The high sensitivity (1,035 μA mM−1 cm−2), low determination (0.2 μM) and large linear range (10-9,300 μM) characteristic of the Cu/Co/CoO/NGC sensor are attributed to the synergistic effect between the Cu, Co and CoO nanoparticles coated by NGC and the catalytically active M-Nx moieties (M = Cu and Co). Importantly, the good stability and antioxidation of the Cu/Co/CoO/NGC electrode result from the protection provided by the NGC shell. In addition, disposable, low-cost, and compact screen-printed carbon electrodes (SPCEs) modified by the Cu/Co/CoO/NGC (Cu/Co/CoO/NGC/SPCEs) were used to detect the sugar content in wine samples with a good reliability (R.S.D. = 1.7%) and recovery (103.2%). Thus, Cu/Co/CoO/NGC/SPCEs will be popular in the detection of real samples.
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spelling curtin-20.500.11937-792742020-08-04T02:49:51Z Nitrogen-doped graphic carbon protected Cu/Co/CoO nanoparticles for ultrasensitive and stable non-enzymatic determination of glucose and fructose in wine He, J. Zhong, Yijun Xu, Q. Sun, H. Zhou, W. Shao, Zongping Science & Technology Physical Sciences Technology Electrochemistry Materials Science, Coatings & Films Materials Science OXYGEN REDUCTION SENSOR NANOCOMPOSITES CU © 2018 The Electrochemical Society. Food safety has always been a very serious and global concern. Content determination of each component is one of the most routine analyses in food testing. Here, nitrogen-doped graphic carbon (NGC)-coated Cu/Co/CoO nanoparticles (Cu/Co/CoO/NGC) show excellent performance for glucose and fructose detection in wine. The high sensitivity (1,035 μA mM−1 cm−2), low determination (0.2 μM) and large linear range (10-9,300 μM) characteristic of the Cu/Co/CoO/NGC sensor are attributed to the synergistic effect between the Cu, Co and CoO nanoparticles coated by NGC and the catalytically active M-Nx moieties (M = Cu and Co). Importantly, the good stability and antioxidation of the Cu/Co/CoO/NGC electrode result from the protection provided by the NGC shell. In addition, disposable, low-cost, and compact screen-printed carbon electrodes (SPCEs) modified by the Cu/Co/CoO/NGC (Cu/Co/CoO/NGC/SPCEs) were used to detect the sugar content in wine samples with a good reliability (R.S.D. = 1.7%) and recovery (103.2%). Thus, Cu/Co/CoO/NGC/SPCEs will be popular in the detection of real samples. 2018 Journal Article http://hdl.handle.net/20.500.11937/79274 10.1149/2.0151813jes English ELECTROCHEMICAL SOC INC fulltext
spellingShingle Science & Technology
Physical Sciences
Technology
Electrochemistry
Materials Science, Coatings & Films
Materials Science
OXYGEN REDUCTION
SENSOR
NANOCOMPOSITES
CU
He, J.
Zhong, Yijun
Xu, Q.
Sun, H.
Zhou, W.
Shao, Zongping
Nitrogen-doped graphic carbon protected Cu/Co/CoO nanoparticles for ultrasensitive and stable non-enzymatic determination of glucose and fructose in wine
title Nitrogen-doped graphic carbon protected Cu/Co/CoO nanoparticles for ultrasensitive and stable non-enzymatic determination of glucose and fructose in wine
title_full Nitrogen-doped graphic carbon protected Cu/Co/CoO nanoparticles for ultrasensitive and stable non-enzymatic determination of glucose and fructose in wine
title_fullStr Nitrogen-doped graphic carbon protected Cu/Co/CoO nanoparticles for ultrasensitive and stable non-enzymatic determination of glucose and fructose in wine
title_full_unstemmed Nitrogen-doped graphic carbon protected Cu/Co/CoO nanoparticles for ultrasensitive and stable non-enzymatic determination of glucose and fructose in wine
title_short Nitrogen-doped graphic carbon protected Cu/Co/CoO nanoparticles for ultrasensitive and stable non-enzymatic determination of glucose and fructose in wine
title_sort nitrogen-doped graphic carbon protected cu/co/coo nanoparticles for ultrasensitive and stable non-enzymatic determination of glucose and fructose in wine
topic Science & Technology
Physical Sciences
Technology
Electrochemistry
Materials Science, Coatings & Films
Materials Science
OXYGEN REDUCTION
SENSOR
NANOCOMPOSITES
CU
url http://hdl.handle.net/20.500.11937/79274