Rh(I)(2,5-norbornadiene)(biphenyl)(tris(4-fluorophenyl)phosphine): Synthesis, Characterization, and Application as an Initiator in the Stereoregular (Co)Polymerization of Phenylacetylenes

Rh(I)(2,5-norbornadiene)(biphenyl)(tris(4-fluorophenyl)phosphine): Synthesis, Characterization, and Application as an Initiator in the Stereoregular (Co)Polymerization of Phenylacetylenes

The synthesis of the Rh(I)-aryl complex, Rh(I)(nbd)(BiPh)(P(4-FC6H4)3) is reported and its efficacy as an initiator for the (co)polymerization of phenylacetylenes established. The X-ray crystal structure indicates that the complex adopts a slightly distorted square planar geometry whose purity and s...

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Bibliographic Details
Main Authors: Loong Tan, N.S., Nealon, G.L., Turner, G.F., Moggach, S.A., Ogden, Mark, Massi, Max, Lowe, Andrew
Format: Journal Article
Language:English
Published: AMER CHEMICAL SOC 2020
Subjects:
Science & Technology
Physical Sciences
Polymer Science
LIVING POLYMERIZATION
RHODIUM CATALYSTS
BLOCK-COPOLYMERS
MOLECULAR-WEIGHT
COMPLEXES
LIGAND
Online Access:http://hdl.handle.net/20.500.11937/77877

Internet

http://hdl.handle.net/20.500.11937/77877

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