Rhodium(I)-a-Phenylvinylfluorenyl Complexes: Synthesis, Characterization, and Evaluation as Initiators in the Stereospecific Polymerization of Phenylacetylene

The synthesis, characterization and use, as initiators for phenylacetylene polymerizations, of three new rhodium(I)-vinyl complexes containing fluorenyl functionality with fluorine-functionalized phosphine ligands is described. Rh(nbd)(CPh=CFlu)P(4-FC6H4)3, Rh(nbd)(CPh=CFlu)P(4-CF3C6H4)3, and Rh(nbd...

Full description

Bibliographic Details
Main Authors: Tan, N., Simpson, Peter, Nealon, G., Sobolev, A., Raiteri, Paolo, Massi, Massimiliano, Ogden, Mark, Lowe, Andrew
Format: Journal Article
Published: Wiley - V C H Verlag GmbH 2019
Online Access:http://hdl.handle.net/20.500.11937/74718