The effect of pyridine modification of Ni-DOBDC on CO2 capture under humid conditions

The metal-organic framework Ni-DOBDC was modified with pyridine molecules to make the normally hydrophilic internal surface more hydrophobic. Experiments and molecular simulations show that the pyridine modification reduces H 2O adsorption while retaining substantial CO2 capacity under the condition...

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Bibliographic Details
Main Authors: Bae, Y., Liu, Jian, Wilmer, C., Sun, H., Dickey, A., Kim, M., Benin, A., Willis, R., Barpaga, D., LeVan, M., Snurr, R.
Format: Journal Article
Published: The Royal Society of Chemistry 2014
Online Access:http://hdl.handle.net/20.500.11937/72519