In Situ Formation of Er0.4Bi1.6O3 Protective Layer at Cobaltite Cathode/Y2O3–ZrO2 Electrolyte Interface under Solid Oxide Fuel Cell Operation Conditions
© Copyright 2018 American Chemical Society. Bismuth-based oxides exhibit outstanding oxygen ionic conductivity and fast oxygen surface kinetics and have shown great potential as a highly active component for electrode materials in solid oxide fuel cells (SOFCs). Herein, a Nb-doped La0.6Sr0.4Co0.2Fe0...
| Main Authors: | , , , , , , , |
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| Format: | Journal Article |
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American Chemical Society
2018
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| Online Access: | http://purl.org/au-research/grants/arc/DP150102025 http://hdl.handle.net/20.500.11937/71096 |
| _version_ | 1848762388699938816 |
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| author | He, Shuai Zhang, Qi Maurizio, Giulio Catellani, Lorenzo Chen, K. Chang, Q. Santarelli, M. Jiang, San Ping |
| author_facet | He, Shuai Zhang, Qi Maurizio, Giulio Catellani, Lorenzo Chen, K. Chang, Q. Santarelli, M. Jiang, San Ping |
| author_sort | He, Shuai |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | © Copyright 2018 American Chemical Society. Bismuth-based oxides exhibit outstanding oxygen ionic conductivity and fast oxygen surface kinetics and have shown great potential as a highly active component for electrode materials in solid oxide fuel cells (SOFCs). Herein, a Nb-doped La0.6Sr0.4Co0.2Fe0.7Nb0.1O3-d (LSCFNb) electrode with 40% Er0.4Bi1.6O3 (ESB) composite electrode was successfully fabricated by decoration method and directly assembled on barrier-layer-free yttrium-stabilized zirconia (YSZ) electrolyte cells, achieving a peak power density of 1.32 W cm-2 and excellent stability at 750 °C and 250 mA cm-2 for 100 h. ESB decoration also significantly reduces the activation energy from 214 kJ mol-1 for the O2 reduction on pristine LSCFNb electrode to 98 kJ mol-1. Further microstructural analysis reveals that there is a redistribution and migration of the ESB phase in the ESB-LSCFNb composite toward the YSZ electrolyte under the influence of cathodic polarization, forming a thin ESB layer at the cathode/YSZ electrolyte interface. The in situ formed ESB layer not only prevents the direct contact and subsequent reaction between segregated SrO and YSZ electrolytes, but also remarkably promotes the oxygen migration/diffusion at the interface for O2 reduction reaction, resulting in a remarkable increase in power output and a decrease in activation energy. The present study clearly demonstrated the in situ formation of a highly functional and active ESB protective layer at LSCFNb cobaltite cathode and YSZ electrolyte interface via ESB-decorated LSCFNb composite cathode under SOFC operation conditions. |
| first_indexed | 2025-11-14T10:46:47Z |
| format | Journal Article |
| id | curtin-20.500.11937-71096 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T10:46:47Z |
| publishDate | 2018 |
| publisher | American Chemical Society |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-710962021-10-19T01:27:02Z In Situ Formation of Er0.4Bi1.6O3 Protective Layer at Cobaltite Cathode/Y2O3–ZrO2 Electrolyte Interface under Solid Oxide Fuel Cell Operation Conditions He, Shuai Zhang, Qi Maurizio, Giulio Catellani, Lorenzo Chen, K. Chang, Q. Santarelli, M. Jiang, San Ping © Copyright 2018 American Chemical Society. Bismuth-based oxides exhibit outstanding oxygen ionic conductivity and fast oxygen surface kinetics and have shown great potential as a highly active component for electrode materials in solid oxide fuel cells (SOFCs). Herein, a Nb-doped La0.6Sr0.4Co0.2Fe0.7Nb0.1O3-d (LSCFNb) electrode with 40% Er0.4Bi1.6O3 (ESB) composite electrode was successfully fabricated by decoration method and directly assembled on barrier-layer-free yttrium-stabilized zirconia (YSZ) electrolyte cells, achieving a peak power density of 1.32 W cm-2 and excellent stability at 750 °C and 250 mA cm-2 for 100 h. ESB decoration also significantly reduces the activation energy from 214 kJ mol-1 for the O2 reduction on pristine LSCFNb electrode to 98 kJ mol-1. Further microstructural analysis reveals that there is a redistribution and migration of the ESB phase in the ESB-LSCFNb composite toward the YSZ electrolyte under the influence of cathodic polarization, forming a thin ESB layer at the cathode/YSZ electrolyte interface. The in situ formed ESB layer not only prevents the direct contact and subsequent reaction between segregated SrO and YSZ electrolytes, but also remarkably promotes the oxygen migration/diffusion at the interface for O2 reduction reaction, resulting in a remarkable increase in power output and a decrease in activation energy. The present study clearly demonstrated the in situ formation of a highly functional and active ESB protective layer at LSCFNb cobaltite cathode and YSZ electrolyte interface via ESB-decorated LSCFNb composite cathode under SOFC operation conditions. 2018 Journal Article http://hdl.handle.net/20.500.11937/71096 10.1021/acsami.8b14026 http://purl.org/au-research/grants/arc/DP150102025 http://purl.org/au-research/grants/arc/DP150102044 http://purl.org/au-research/grants/arc/DP180100731 http://purl.org/au-research/grants/arc/DP180100568 American Chemical Society fulltext |
| spellingShingle | He, Shuai Zhang, Qi Maurizio, Giulio Catellani, Lorenzo Chen, K. Chang, Q. Santarelli, M. Jiang, San Ping In Situ Formation of Er0.4Bi1.6O3 Protective Layer at Cobaltite Cathode/Y2O3–ZrO2 Electrolyte Interface under Solid Oxide Fuel Cell Operation Conditions |
| title | In Situ Formation of Er0.4Bi1.6O3 Protective Layer at Cobaltite Cathode/Y2O3–ZrO2 Electrolyte Interface under Solid Oxide Fuel Cell Operation Conditions |
| title_full | In Situ Formation of Er0.4Bi1.6O3 Protective Layer at Cobaltite Cathode/Y2O3–ZrO2 Electrolyte Interface under Solid Oxide Fuel Cell Operation Conditions |
| title_fullStr | In Situ Formation of Er0.4Bi1.6O3 Protective Layer at Cobaltite Cathode/Y2O3–ZrO2 Electrolyte Interface under Solid Oxide Fuel Cell Operation Conditions |
| title_full_unstemmed | In Situ Formation of Er0.4Bi1.6O3 Protective Layer at Cobaltite Cathode/Y2O3–ZrO2 Electrolyte Interface under Solid Oxide Fuel Cell Operation Conditions |
| title_short | In Situ Formation of Er0.4Bi1.6O3 Protective Layer at Cobaltite Cathode/Y2O3–ZrO2 Electrolyte Interface under Solid Oxide Fuel Cell Operation Conditions |
| title_sort | in situ formation of er0.4bi1.6o3 protective layer at cobaltite cathode/y2o3–zro2 electrolyte interface under solid oxide fuel cell operation conditions |
| url | http://purl.org/au-research/grants/arc/DP150102025 http://purl.org/au-research/grants/arc/DP150102025 http://purl.org/au-research/grants/arc/DP150102025 http://purl.org/au-research/grants/arc/DP150102025 http://hdl.handle.net/20.500.11937/71096 |