Mixed-metal cluster chemistry. 37. Syntheses, structural, spectroscopic, electrochemical, and optical power limiting studies of tetranuclear molybdenum-iridium clusters

Mixed-metal cluster chemistry. 37. Syntheses, structural, spectroscopic, electrochemical, and optical power limiting studies of tetranuclear molybdenum-iridium clusters

Tetrahedral Mo2Ir2(μ3-CO)(μ-CO)5(CO)4(η5-C5H5)2 (1) reacted with P(C6H4Me-4)3, P(C6H2Me2-3,5-OMe-4)3, and AsPh3 to afford the substitution products Mo2Ir2(μ-CO)3(CO)6(L)(η5-C5H5)2 [L = P(C6H4Me-4)3 (3), P(C6H2Me2-3,5-OMe-4)3 (4), AsPh3 (5)] in fair to good yields, while reaction of 1 with HC≡CSiPri3...

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Bibliographic Details
Main Authors: Fu, J., Moxey, G., Morshedi, M., Barlow, A., Randles, M., Simpson, Peter, Schwich, T., Cifuentes, M., Humphrey, M.
Format: Journal Article
Published: Elsevier 2015
Online Access:http://hdl.handle.net/20.500.11937/6018

Internet

http://hdl.handle.net/20.500.11937/6018

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